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  • Nonlinear Crystal BIBO Crystals
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  • Nonlinear Crystal BIBO Crystals

Nonlinear Crystal BIBO Crystals

Nonlinear Crystal BIBO( BiB3O6) crystal is a newly developed nonlinear Optical Crystal. It possesses large effective nonlinear coefficient, high damage threshold and inertness with respect to moisture.
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BIBO Crystals
BIBO( BiB3O6) crystal is a newly developed nonlinear Optical Crystal. It possesses large effective nonlinear coefficient, high damage threshold and inertness with respect to moisture. Its nonlinear coefficient is 3.5-4 times higher than that of LBO,1.5-2 times higher than that of BBO. It is a promising doubling crystal to produce blue laser. The top-seeded solution growth (TSSG) technique is used for the growth of BIBO single crystals.  Large crystal size up to 10x10x15mm  AR coating, mounts and re-polishing service

Feature
Broad transparent range from 286nm to 2500nm
Large effective SHG coefficient (~ 9 times that of KDP)
High damage threshold
Maximum aperture: 15x15mm

Specifications:
Clear Aperture central 90% of the diameter Flatness less than λ/8 @ 633nm
Transmitting Wavefront Distortion less than λ/8 @ 633nm Chamfer ≤0.2mmx45°
Chip ≤0.1mm Surface Quality 10/ 5 S/D to MIL-PRF-13830B
Parallelism better than 20 arc seconds Perpendicularity ≤5 arc minutes
Angle Tolerance Δθ≤0.25°, ΔΦ≤0.25° Quality Warranty Period one year under proper use

 

Chemical and Structure Properties:

Crystal Structure Monoclinic, Point group 2 Lattice Parameter a=7.116Å,b=4.993Å, c=6.508Å, β=105.62° ,Z=2
Melting Point 726°C Mohs Hardness 5-5.5
Density 5.033 g/cm3 Thermal Expansion Coefficient αa=4.8x10-5 /K, αb=4.4x10-6 /K, αc=-2.69x10-5 /K

 

Optical and Nonlinear Optical Properties:

Transparency Range 286-2500nm Absorption Coefficient <0.1%/cm at 1064nm
Physical Axis X//b,(Z,a)=31.6°,(Y,c)=47.2° SHG of 1064/532 Phase matching angle:168.9° from z axis in YZ plane
Deff:3.0+/-0.1 pm/V
Angular acceptance:2.32 arad-cm
Walk-off angle :25.6 mrad
temperature acceptance:2.17°C-cm

 

Sellmeier Coefficients ni2(λ)=A+B / (λ2-C)-Dλ2 (λ in um)
  A B C D
n1 3.6545(4) 0.0511(2) 0.0371(3) 0.0226(1)
n2 3.0740(3) 0.0323(1) 0.0316(3) 0.01337(6)
n3 3.1685(3) 0.0373(1) 0.0346(3) 0.01750(8)
 

Typical Applications:

SHG and THG for middle and high power1064 nm Nd: lasers
SHG and THG for high power Nd: lasers at 1342 &1319 nm for red and blue laser
Over 2.8 W CW blue laser at 473 nm was obtained from frequency doubling of 4.6 W CW Nd: YAG at 946 nm with BiBO
Optical Parametric Amplifiers (OPA) and Oscillators (OPO)

Comparison Of Nonlinear Optical Properties Of Crystals For SHG @ 946 Nm

Crystals Length
(mm)
Deff
(pm/V)
Walk-off
(mrad)
Output Power(W) Conversion  Efficiency
BiBO 10.4 3.3 40.7 2.8 63%
LBO 10 0.81 11.3 1.52 33%
BBO 8 2.0 60.3 2.1 47%

WDQ Optics can provide the perfect polishing surface and do the coating according to the customer's requirements.

Capabilities:

Aperture: 2x2 ~ 25x25mm
Length: 0.1 - 20mm
Cutting Angle q and f: Determined by different kinds of harmonic generation
Phase matching type: Type I or Type II
End Configuration: Plano/Plano or Brewster/Brewster or Specified

WDQ Optics Offer Standard BIBO Crystal Within 5 Weeks.

Dimension Application Coating Type
3x3x5mm SHG or THG AR coating I
3x3x7mm SHG or THG AR coating I
3x3x10mm SHG or THG AR coating I
4x4x10mm SHG or THG AR-coating I

 
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