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  • Nonlinear Crystal ZGP (ZnGeP2) Crystals
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  • Nonlinear Crystal ZGP (ZnGeP2) Crystals

Nonlinear Crystal ZGP (ZnGeP2) Crystals

Nonlinear Crystal Zinc germanium phosphide (ZnGeP2) is an excellent mid-IR nonlinear crystal with many outstanding fundamental properties.
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  • Description
ZGP (ZnGeP2) Crystals
ZnGeP2 (zinc germanium phosphide) crystals have a number of good properties, and is in the infrared nonlinear crystal. The nonlinear susceptibility of ZnGeP2 (ZGP) crystal is about 160 times that of KDP (d36~75 pm/V). ZGP shows good optical transparency at 0.74-12 mm, and has a relatively high laser damage threshold, so it is very suitable for the production of near-infrared tunable lasers. ZGP is a very promising material for mid-infrared equipment such as SHG, SFG, OPO and OPG/OPA.

Feature
Wide transmission region from 0.74μm to 12μm
Large nonlinear coefficient
Phase matchable over a broad spectral region
Applications: SHG, SFG, OPO and OPG/OPA in the mid-infrared region

Applications:
Second, third, and fourth harmonic generation of CO2 laser
Optical parametric generation (OPO) with pumping at a wavelength of 2.05-2.94μm and the possibility to generate effectively 3-10μm ranges
Second-harmonic generation of CO-laser
Producing coherent radiation in sub-millimeter-range from 70.0μm to 1000μm - terahertz range
Generation of combined frequencies of CO2- and CO-lasers radiation and other lasers are working in the crystal transparency region


Specifications:

Materials ZnGeP2 crystals Thickness Tolerance +/-0.05mm
Orientation Tolerance <0.5° Flatness less than λ/8 @ 633nm
Transmitting Wavefront Distortion less than λ/4 @ 633nm Chamfer ≤0.2mmx45°
Chip ≤0.1mm Surface Quality better than 10/5 S/D (MIL-PRF-13830B)
Parallelism ≤30 arc seconds Perpendicularity ≤15 arc minutes
Aperture >90%  

 

Chemical and Physical Properties:

Chemical Formula ZnGeP2 Crystal Structure Tetragonal, 42m
Lattice Parameter a=b=5.467Å, c=12.736Å Mass Density 4.16 g/cm3
Moh Hardness 5.5 Melting Point About 1040°C
Thermal Conductivity 180 W/m/K Thermal Expansion Coefficient β,5x10-6 /K; β⊥,7.8x10-6 /K
Birefringence Positive uniaxial  

 

Linear Optical Properties

Transparency range 0.74 - 12μm
Absorption coefficient α<0.05cm-1 @2050-2100nm
Refractive Indices
@ 2.05 μm
@ 2.79 μm
@ 5.30 μm
@ 10.6 μm
no = 3.1478, ne = 3.1891
no = 3.1333, ne = 3.1744
no = 3.1136, ne = 3.1547
no = 3.0729, ne = 3.1143
Sellmeier Equations(λ in μm) no2(λ) = 4.64467+5.10087/(λ2-0.13656)+4.27777λ2/(λ2-1653.89)
ne2(λ) = 4.71539+5.26358/(λ2-0.14386)+2.37310λ2/(λ2-1000.82)

 

Nonlinear Optical Properties

SHG Phase Matchable 3177 ∼ 10357nm (Type I)
NLO coefficients d36=75 ± 8 pm/V
Type Ⅰ deeo=d36 sin2ϴcos2φ
Type Ⅱ doeo=deoo=d36 sinϴsin2φ
Damage Threshold
at 2.79 μm 30 GW/cm2 (150 ps)
at 10.6 μm 1 GW/cm2 (2 ns)

Modules or Types:

Modules Crystal Dimension Application Orientation Theta/Phi deg Coatings
ZGP-7515-54 7x5x15mm OPO @ 2.1-> 3.5-5 µm 54/0 AR@2.1µm+BBAR@3.5-5µm
ZGP-7520-54 7x5x20mm OPO @ 2.1-> 3.5-5 µm 54/0 AR@2.1µm+BBAR@3.5-5µm
ZGP-7525-54 7x5x25mm OPO @ 2.1-> 3.5-5 µm 54/0 AR@2.1µm+BBAR@3.5-5µm

 
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